ISSN 0862-5468 (Print), ISSN 1804-5847 (online) 

Ceramics-Silikáty 48, (1) 6 - 13 (2004)


FUNDAMENTAL CONSIDERATIONS ON SUSPENSION RHEOLOGY
 
Pabst Willi
 
Department of Glass and Ceramics, Institute of Chemical Technology Prague, Technická 5, 166 28 Prague 6, Czech Republic

Keywords: Suspension rheology, Effective viscosity, Dilute suspensions, Critical volume fraction
 

The basic assumptions of suspension rheology (existence of a unique viscosity and dependence of the effective viscosity on the solids volume fraction) are discussed from the viewpoint of rational mechanics and micromechanics. The most important effective viscosity formulae are presented in a new way, which clarifies the status of these formulae and makes a clear distinction between exponential (Mooney-type) relations and power-law (Krieger-type) relations. Based on a functional equation approach, a tentative explanation is given why the latter are more successful. The Frankel-Acrivos relation is modified to exhibit correct behavior in the dilute limit.


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