ISSN 0862-5468 (Print), ISSN 1804-5847 (online) 

Ceramics-Silikáty 43, (3) 111 - 116 (1999)


CHEMICAL ACTIVATION OF SUBSTANCES WITH LATENT HYDRAULIC PROPERTIES
 
Škvára František, Bohuněk Jan
 
Department of Glass and Ceramics, Institute of Chemical Technology, Prague Technická 5, 166 28 Prague

Alkaline activation (brought about by the effect of NaOH and Na₂SiO₃ solutions) is capable of increasing significantly the reactivity of substances with latent hydraulic properties, such as fly-ash or mixtures of fly-ash with blast-furnace slag. The optimum properties (compressive strength of 120 - 170 MPa) were achieved with ash-slag mixtures over the composition range 70 - 50 wt.% fly-ash and 30 - 50 wt.% slag, activated with alkaline activator having a MS modulus of 0.6 and containing 7 wt.% Na₂O. The microstructure of hardened activated fly-ash and ash-slag mixtures is composed of amorphous hydrates of sodium aluminosilicates and the C-S-H phase.


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