Ceramics-Silikáty 14, (1) 1 - 16 (1970) |
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DISSOLVING OF VITREOUS SiO₂ IN VARIOUS TYPES OF GLASS MELTS UNDER CONDITIONS OF FREE CONVECTION |
Truhlářová Marie, Vepřek Otakar |
Joint Laboratory for the Chemistry and Technology of Silicates, Czechoslovak Academy of Sciences and Chemical-Technological Technical University, Prague
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Dissolving of quartz glass in the following glass melts has been examined with the aim of establishing experimentally the corrosion mechanism of refractories with glass melts:
1. Na₂O-SiO₂
2. Na₂O-CaO-SiO₂
3. K₂O-PbO-SiO₂
4. Na₂O-B₂O₃-SiO₂
5. CaO-Al₂O₃-SiO₂
The dissolution rate under the conditions of free convection was measured for Na₂O-SiO₂ melts within the 1050-1250 °C temperature range, and for the other melts within the 1200-1500 °C temperature interval. Diffusion coefficients have been calculated for the Na₂O-SiO₂ melts and for the Na₂O-CaO-SiO₂ ones. The diffusion coefficients for the other glass melts could not be calculated as only insufficient amounts of data were available.
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