ISSN 0862-5468 (Print), ISSN 1804-5847 (online) 

Ceramics-Silikáty 38, (2) 85 - 91 (1994)


CALCULATION OF HENRY´S CONSTANTS OF ADSORPTION OF NOBLE GASES ON IDEALIZED SURFACE OF TALC
 
Turi Nagy Ladislav, Tunega Daniel, Liška Marek
 
Institute of Inorganic Chemistry, Slovak Academy of Sciences, Dúbravská cesta 9, 842 36 Bratislava, Slovak republic

The proportionality constants between the gas pressure and occupancy of the idealized talc surface were computed for noble gases Helium, Neon, Argon, Krypton and Xenon covering the temperature range 100 K - 450 K. Interaction potencial noble gas atom - solid phase was calculated using summation of interaction potencials of Lennard-Jones type. The values of Henry´s constants of adsorption were calculated using known formula based on computation of configuration integral. The one-particle configuration integral was calculated using the classical mechanics limit. The assumption of ideality of both, free gas and adsorbed phase, was used. The obtained values of Henry´s constant are in quantitative agreement with the values estimated from experimental absorption isotherms for analogical systems.


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